ChemInform Abstract: A New Intersecting Tunnel Structure in the A^IM^III[PO₃(OH)]₂ Series for A^I = Ag, M^III = In: Analysis of Structural Relationships.

Abstract

AgIn[PO 3 (OH)] 2 is hydrothermally synthesized from an aqueous mixture of AgNO3, In2O3, and H3PO4 in the molar ratio of 1:1.5:6 (autoclave, 220°C, 36 h). The new compound crystallizes in the space group P21/c with Z = 4 (single crystal XRD). Its three-dimensional framework contains corner-sharing PO3(OH) tetrahedra and InO6 octahedra forming intersecting tunnels in which the Ag + cations are located. -(GUESDON*, A.; ROMERO SARRIA, F.; TENAILLEAU, C.; RAVEAU, B.; Solid State