Chemischer Informationsdienst
 1979
DOI: 10.1002/chin.197921153
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ChemInform Abstract: ACID‐CATALYZED HYDRATION OF DI‐TERT‐BUTYLKETENE

Shaikh H. Kabir1,
Hani R. Seikaly2,
Thomas T. Tidwell3

Abstract: Die bei der säurekatalysierten Hydratisierung der Titelverbindung in wäßrigem Acetonitril in Gegenwart von HCOOH‐HCOONa‐Puffer bei pH 4.09, von HCl‐KH2PO4‐Puffer bei pH 3.30 bzw. von H2SO4 ermittelten Geschwindigkeitskonstanten weisen für die Bildung von Ditert.‐butyl‐essigsäure auf einen Protonübertragungsmechanismus hin.

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