Chemischer Informationsdienst
 1980
DOI: 10.1002/chin.198018290
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ChemInform Abstract: ACID‐CATALYZED REACTIONS OF 1α,2α‐EPOXY‐1β‐METHYL‐ AND 1α‐HYDROXY‐1β‐METHYL 5α‐STEROIDS

I. Torrini1,
Anna M. Maione2,
A. Calcagni3

Abstract: Die Reaktion des Epoxyandrostandioldiacetates (I) mit BF3 ‐ Et; O führt zu dem A‐Norsteroid (II) und dem 1‐Methylen‐Derivat (IIIa), mit Tos‐OH bei 20 bzw. 100°C zu (IIIb) bzw. (IIIe), und mit HCOOH zu dem Formiat (IIId).

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