Chemischer Informationsdienst. Organische Chemie
 1971
DOI: 10.1002/chin.197120030
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ChemInform Abstract: ARBUZOV‐UMLAGERUNG IN DER REIHE AROMATISCHER KATIONEN

S. V. Krivun1,
S. N. Baranov2,
O. F. Voziyanova3

Abstract: Triäthylphosphit (II) setzt sich bei 100°C mit in γ‐Stellung nicht substituierten Pyriliumhalogeniden, z.B. mit 2,6‐Diaryl‐pyrilium‐bromid (I), unter Abdestillieren von Äthylbromid zu Pyranyl‐phosphonsäure‐diäthylestern (III) um.

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