ChemInform Abstract: BASIZITAET UND ELEKTRONENSPEKTREN VON 3′‐AMINO‐ UND 4′‐AMINO‐4‐DIMETHYLAMINO‐AZOBENZOLEN

Korolev, B. A.; Titova, S. P.; Ufimtsev, V. N.

doi:10.1002/chin.197139092

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“…For instance, absorption bands of 4-hydroxyazobenzene are recorded at 344 and 425 nm in CH 3 CN. 42 In 4-aminoazobenzene, both absorption bands overlap to form a broad band 43 with a maximum at 382 nm in CH 3 CN. 44 NMR Studies.…”

Section: Resultsmentioning

confidence: 99%

Synthesis and Reactivity of [closo-1-CB₉H₉-1-N₂]: Functional Group Interconversion at the Carbon Vertex of the {closo-1-CB₉} Cluster

2009

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The dinitrogen derivative [closo-1-CB(9)H(9)-1-N(2)] (1) was prepared from amine [closo-1-CB(9)H(9)-1-NH(3)] (2) and reacted with three types of nucleophiles: activated arenes (phenolate and aniline), divalent sulfur compounds (Me(2)S and Me(2)NCHS), and pyridine, giving products of substitution at C(cage). The reaction of 1 with pyridine gave all four isomers 11a-11d, indicating the Gomberg-Bachmann mechanism, which involves radical anion [closo-1-CB(9)H(9)](-*) (26). The radical and also closed-shell electrophilic aromatic substitution mechanisms were probed with the aid of DFT and MP2 computational methods and compared to those of phenylation of pyridine. Overall, experimental results supported by computational analysis suggest two mechanisms for the substitution of the N(2) group in 1: (i) thermal heterolytic cleavage of the C(cage)-N bond and the formation of electrophilic carbonium ylide [closo-1-CB(9)H(9)] (19) and (ii) electron-transfer-induced homolytic cleavage of the C(cage)-N bond and the formation of 26. Decomposition of 1 in MeCN is believed to proceed by the nonradical mechanism involving formation of the ylide 19 as the rate-determining step with experimental activation parameters DeltaH(double dagger) = 38.4 +/- 0.8 kcal mol(-1) and DeltaS(double dagger) = 44.5 +/- 2.5 cal mol(-1) K(-1). The electron-transfer-induced formation of 26 is consistent with the relatively high reduction potential of 1 (E(pc) = -0.54 V), which is more cathodic than that of PhN(2)(+) by 0.38 V. Transformations of the phenol 8a and the Me(2)NCHS adduct 10 were demonstrated by O-methylation of the former and hydrolysis of 10 followed by S-alkylative cyclization. Direct products and their derivatives were investigated by UV-vis spectroscopy and analyzed with the ZINDO computational method.

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Section: Resultsmentioning

confidence: 99%

Synthesis and Reactivity of [closo-1-CB₉H₉-1-N₂]: Functional Group Interconversion at the Carbon Vertex of the {closo-1-CB₉} Cluster

2009

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ChemInform Abstract: BASIZITAET UND ELEKTRONENSPEKTREN VON 3′‐AMINO‐ UND 4′‐AMINO‐4‐DIMETHYLAMINO‐AZOBENZOLEN

Cited by 1 publication

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Synthesis and Reactivity of [closo-1-CB₉H₉-1-N₂]: Functional Group Interconversion at the Carbon Vertex of the {closo-1-CB₉} Cluster

Synthesis and Reactivity of [closo-1-CB₉H₉-1-N₂]: Functional Group Interconversion at the Carbon Vertex of the {closo-1-CB₉} Cluster

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ChemInform Abstract: BASIZITAET UND ELEKTRONENSPEKTREN VON 3′‐AMINO‐ UND 4′‐AMINO‐4‐DIMETHYLAMINO‐AZOBENZOLEN

Cited by 1 publication

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Synthesis and Reactivity of [closo-1-CB9H9-1-N2]: Functional Group Interconversion at the Carbon Vertex of the {closo-1-CB9} Cluster

Synthesis and Reactivity of [closo-1-CB9H9-1-N2]: Functional Group Interconversion at the Carbon Vertex of the {closo-1-CB9} Cluster

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Synthesis and Reactivity of [closo-1-CB₉H₉-1-N₂]: Functional Group Interconversion at the Carbon Vertex of the {closo-1-CB₉} Cluster

Synthesis and Reactivity of [closo-1-CB₉H₉-1-N₂]: Functional Group Interconversion at the Carbon Vertex of the {closo-1-CB₉} Cluster