In aqueous acetic acid, 2,3-diamino-1,4-naphthoquinone reacted with phthalic anhydride and 4,5,6,7tetrabromophthalic anhydride to give naphtho [2',3':4,5]imidazo[2,1-a]isoindole-6,11,13-triones. In the same solvent, the reaction of diaminonaphthoquinone with 2,2-dihydroxy-1H-indene-1,3(2H)-dione gave 11H-benzo[g]indeno [1,2-b]quinoxaline-6,11,13-trione. Under the same conditions, diaminonaphthoquinone reacted with succinic anhydride and with maleic anhydride, the corresponding 4-(3-amino-1,4-dioxo-1,4-dihydronaphthalene-2-ylamino)-4-oxobutanoic acid and 3,5,10-trioxo-3,4,5,10-tetrahydrobenzo[g]-quinoxaline-2(1H)-ylidene-acetic acid derivatives were obtained. The reaction of 2,3-diamino-1,4-naphthoquinone with (E)-1,2-dibenzoylethylene and 1,4diphenylbut-2-yne-1,4-dione in aqueous acetic acid afforded dihydrobenzo[g]quinoxaline-5,10-diones.