ChemInform Abstract: Bimetallic Alkoxides of Zinc and Aluminum.

Aggrawal, M.; Mehrotra, R. C.

doi:10.1002/chin.198830256

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“…Various heteronuclear aluminum alcoholates were investigated by Mehrotra and co-workers in several studies. [29][30][31][32][33][34][35][36][37][38][39][40][41][42][43][44][45][46][47][48] Starting from water-free metal chlorides, compounds like [M{Al(OR) 4 ary alcohols [Equation (2)]. [49] For shifting the equilibrium to the product side, the liberated isopropyl alcohol is distilled off.…”

Section: Introductionmentioning

confidence: 99%

“…tBuOH, the alkoxide ligands cannot be substituted quantitatively. [30] Most of such compounds investigated by Mehrotra and co-workers appear as volatile viscous liquids, except derivatives containing tertiary alkoxides, which form solids. Another possibility to substitute iso-propanolate ligands by other alkoxides is a transesterification reaction [Equation (3)].…”

Section: Introductionmentioning

confidence: 99%

See 1 more Smart Citation

Synthesis, Crystal Structures, and Thermolysis Studies of Heteronuclear Transition Metal Aluminum Alcoholates

Küsel

Krautscheid

2020

Zeitschrift anorg allge chemie

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Heteronuclear alcoholate complexes [M{Al(OiPr) 4 } 2 (bipy)] (2-M, M = Fe, Co, Ni, Cu, Zn) and [M{Al(OcHex) 4 } 2 (bipy)] (3-M, M = Fe, Co, Ni, Zn) are formed by adduct formation of [M{Al(OiPr) 4 } 2 ] (1-M, M = Fe, Co, Ni, Cu, Zn) with 2,2Ј-bipyridine and transesterification reaction with cHexOAc. According to crystal structure analyses, in 2-M and 3-M the central transition metal ion M 2+ is coordinated by two chelating Al(OR) 4 moieties and one bipyr

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