ChemInform Abstract: Borylation of Unactivated Aryl Chlorides under Mild Conditions by Using Diisopropylaminoborane as a Borylating Reagent.

Abstract

Palladium‐catalyzed coupling between aryl chlorides and diisopropylaminoborane leads to the formation of a C—B bond under mild conditions and in the presence of pinacol, the corresponding pinacol boronate esters are obtained in high yields.