ChemInform Abstract: Calcium‐Mediated Hydrophosphorylation of Organic Isocyanates with Diphenylphosphane Oxide.

Abstract

The reaction of diphenylphosphane oxide (I) with isocyanates (II) and isothiocyanates (IV) in the presence of a calcium catalyst leads to desired formamides (III) and thioformamides (V), respectively. -(HAERLING, S.; GREISER, J.; AL-SHBOUL, T. M. A.; GOERLS, H.; KRIECK, S.; WESTERHAUSEN*, M.; Aust. J. Chem. 66 (2013) 10, 1264-1273, http://dx.