1989
DOI: 10.1002/chin.198940103
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ChemInform Abstract: Carbonyliron‐Olefin Photochemistry: Quantum Yields for the Sequential Substitution of Two CO Groups in Pentacarbonyliron by (E)‐Cyclooctene. Synthesis of the First Stable (η:2‐Olefin)3Fe(CO)2 Complex.

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“…Obvious examples are photoinduced carbonyliron-catalyzed processes, such as olefin isomerization or hydrogenation, 85 where the Fe(CO) 3 moiety plays a key role as the repeating unit in the catalytic cycle. Another interesting case is the single-photon conversion of Fe(CO) 5 into mixtures of mono-and disubstituted derivatives of type Fe(CO) 4 L and Fe(CO) 3 L 2 (L ) mono-olefin or phosphorus ligands), 58,[84][85][86][87] where the addition of two ligands L to the doubly unsaturated Fe(CO) 3 (solv) fragment can now be considered as the most simple route to the Fe(CO) 3 L 2 products. Competitive trapping of Fe(CO) 3 -(solv) by Fe(CO) 5 may occur in case of high Fe(CO) 5 :L ratios.…”
Section: Discussionmentioning
confidence: 99%
“…Obvious examples are photoinduced carbonyliron-catalyzed processes, such as olefin isomerization or hydrogenation, 85 where the Fe(CO) 3 moiety plays a key role as the repeating unit in the catalytic cycle. Another interesting case is the single-photon conversion of Fe(CO) 5 into mixtures of mono-and disubstituted derivatives of type Fe(CO) 4 L and Fe(CO) 3 L 2 (L ) mono-olefin or phosphorus ligands), 58,[84][85][86][87] where the addition of two ligands L to the doubly unsaturated Fe(CO) 3 (solv) fragment can now be considered as the most simple route to the Fe(CO) 3 L 2 products. Competitive trapping of Fe(CO) 3 -(solv) by Fe(CO) 5 may occur in case of high Fe(CO) 5 :L ratios.…”
Section: Discussionmentioning
confidence: 99%