ChemInform Abstract: CATALYSIS OF THE HYDROSILYLATION OF UNSATURATED HYDROCARBONS BY METAL CARBONYLS

Андрианов, К. А.; Magomedov, G. K.‐I.; Shkol'nik, O. V.; Izmailov, K. A.; Морозова, Л. В.; Калинин, В. Н.

doi:10.1002/chin.197651241

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1981

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“…The hydrosilylation of 1-hexyne by triethylsilane catalyzed by chloroplatinic acid or octacarbonyldicobalt(0) has been reported to yield trans-1-triethylsilyl-1-hexene and 2-triethylsilyl-1-hexene (eq. 1) [1,2]. The trans-1triethylsilyl-1-hexene being formed by cis-addition of the silane.…”

Section: Introductionmentioning

confidence: 99%

Hydrosilylation of 1-pentyne by triethylsilane catalyzed by phosphine-rhodium complexes

Brady

Nile

1981

Journal of Organometallic Chemistry

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Made available courtesy of Elsevier: http://www.elsevier.com/ ***Reprinted with permission. No further reproduction is authorized without written permission from Elsevier. This version of the document is not the version of record. Figures and/or pictures may be missing from this format of the document.*** Summary: The hydrosilylation of 1-pentyne by triethylsilane has been investigated using rhodium catalysts, formed by displacement of cyclooctene from dichlorotetrakis(cyclooctene)dirhodium(I) by various molar ratios of phosphines. The results are interpreted in terms of isomerization of an intermediate vinylrhodium complex.

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Section: Introductionmentioning

confidence: 99%

Hydrosilylation of 1-pentyne by triethylsilane catalyzed by phosphine-rhodium complexes

Brady

Nile

1981

Journal of Organometallic Chemistry

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ChemInform Abstract: CATALYSIS OF THE HYDROSILYLATION OF UNSATURATED HYDROCARBONS BY METAL CARBONYLS

Abstract: Als Katalysator für die Anlagerung von Hydroalkylsilan an ungesättigte Kohlenwasserstoffe gilt allgemein Platinchlorwasserstoffsäure als am besten geeignet.

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Hydrosilylation of 1-pentyne by triethylsilane catalyzed by phosphine-rhodium complexes

Hydrosilylation of 1-pentyne by triethylsilane catalyzed by phosphine-rhodium complexes

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