ChemInform Abstract: Chemical and Electrochemical Redox Transformations of Oxomolybdenum and Oxotungsten Tetrathiolate Complexes.

Abstract

The anionic title complexes are readily prepared by the reaction of MOCl4 (Ia) in MeCN or of MCl4(NCMe)2 (Ib) in wet MeCN with the Li thiolate and isolated as their ammonium or phosphonium salts (II) (no yields given).