ChemInform Abstract: COBALT(III) ALKYLPEROXY COMPLEXES. SYNTHESIS, X‐RAY STRUCTURE, AND ROLE IN THE CATALYTIC DECOMPOSITION OF ALKYL HYDROPEROXIDES AND IN THE HYDROXYLATION O HYDROCARBONS

Several novel substituted bis(2‐pyridylimino)isoindolato (BPI) cobalt(II) and iron(II) complexes [M(BPI)(OAc)(H2O)] (M = Co: 1 ‐ 6, Fe: 7) have been synthesized by reaction of bis(2‐pyridylimino)isoindole derivatives with the corresponding metal(II) acetates. Reaction of 1‐6 with 1.5 ‐ 2 molar equivalents of t‐BuOOH gave the corresponding alkylperoxocobalt(III) complexes [Co(BPI)(OAc)(OOtBu)] (10 ‐ 15). Using an aqueous solution of t‐BuOOH (70 %), cyclohexene was selectively catalytically oxidized to the dialkylperoxide cyclohex‐2‐ene‐1‐t‐butylperoxide.

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Allylic Peroxidations with Bis(2‐pyridylimino)isoindolato‐Cobalt and ‐Iron Complexes

Meder

Siggelkow

Gade

2004

Zeitschrift anorg allge chemie

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ChemInform Abstract: COBALT(III) ALKYLPEROXY COMPLEXES. SYNTHESIS, X‐RAY STRUCTURE, AND ROLE IN THE CATALYTIC DECOMPOSITION OF ALKYL HYDROPEROXIDES AND IN THE HYDROXYLATION O HYDROCARBONS

Abstract: Die Co(III)‐alkylperoxy‐Komplexe (II), (IV) und (VI) werden wie aufgezeichnet dargestellt und durch physikochemische Methoden charakterisiert.

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Allylic Peroxidations with Bis(2‐pyridylimino)isoindolato‐Cobalt and ‐Iron Complexes

Allylic Peroxidations with Bis(2‐pyridylimino)isoindolato‐Cobalt and ‐Iron Complexes

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