Chemischer Informationsdienst
 1981
DOI: 10.1002/chin.198123124
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ChemInform Abstract: COPE INTERCONVERSIONS OF THE 9‐METHOXY‐ENDO‐TRICYCLO(4.2.1.02,5)NONA‐3,7‐DIENYL CATION AND ITS (4.3.0.02,5) TAUTOMER. EVIDENCE OF ENHANCED IONIC STABILITY BY DELOCALIZATION OF NEIGHBORING Σ BONDS

Pieter E. Schipper1,
J. W. DE HAAN2,
H. M. BUCK3

Abstract: Lösen des endo‐Diens (Ia) in flüssigem SO2 führt zu einem Dissoziationsgleichgewicht unter Beteiligung des umgelagerten Kations (IVa)/(IVb) (einheitliche Struktur).

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