ChemInform Abstract: Diastereoselectivity Control of the Radical Carboazidation of Substituted Methylenecyclohexanes.

Abstract

Cyclohexane derivatives Q 0040 Diastereoselectivity Control of the Radical Carboazidation of Substituted Methylenecyclohexanes. -The nature and position of the substituents influence the stereoselective outcome of the title reaction. The introduction of bulky or axial groups at position 2 allows highly stereoselective carboazidation. -(CREN, S.; SCHAER, P.; RENAUD*, P.; SCHENK, K.; J. Org. Chem. 74 (2009) 8, 2942-2946; Inst. Chem. Biochem., Univ. Bern, CH-3012 Bern, Switz.; Eng.) -Jannicke 35-063