ChemInform Abstract: Dimerization of Cyclopropanecarbonitrile Mediated by Grignard Reagents. Formation of Highly Substituted Pyridines.

Abstract

Dimerization of Cyclopropanecarbonitrile Mediated by GrignardReagents. Formation of Highly Substituted Pyridines. -Formation of the title compounds is observed in the course of studies on the chemistry of nucleophilic reactions involving 1,1-dicyanoallyl anions, after changing the solvent from Et 2 O to THF. The structure of compound (V) is determined by X-ray crystallographic analysis. -(KOLSAKER, P.; SONGE, P.; ROEM-MING, C.; Acta Chem.