ChemInform Abstract: Direct Synthesis of Highly Substituted Pyrroles and Dihydropyrroles Using Linear Selective Hydroacylation Reactions.

Abstract

A broad spectrum of aldehyde substrates bearing mostly additional ‐S‐Me functions reacts with propargylic amines in the presence of RHC under modified conditions A), C), D) or E) to produce linear hydroacylation adducts with high selectivity.