ChemInform Abstract: Effects of Hetero Atom Substituents in the Decomposition of Pyrazolines: Abnormal Behavior of Methoxy Group Compared with Arylthio or Arylseleno Group.

Hamaguchi, Masashi; Furusawa, Toshiya; Nagai, Toshikazu

doi:10.1002/chin.198652164

Chemischer Informationsdienst

1986

DOI: 10.1002/chin.198652164

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ChemInform Abstract: Effects of Hetero Atom Substituents in the Decomposition of Pyrazolines: Abnormal Behavior of Methoxy Group Compared with Arylthio or Arylseleno Group.

Masashi Hamaguchi¹,

Toshiya Furusawa²,

Toshikazu Nagai³

Abstract: Die durch Addition der Diazoalkane (II) an den Methoxymethylenmalonester (I) zugänglichen Pyrazoline (IIIa)‐(IIIc) und (IIIe) liefern bei der Thermolyse infolge Wasserstoff‐Wanderung bzw. Migration der Methoxygruppe die Methylenmalonester (IV) bzw. (V).

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ChemInform Abstract: Effects of Hetero Atom Substituents in the Decomposition of Pyrazolines: Abnormal Behavior of Methoxy Group Compared with Arylthio or Arylseleno Group.

Abstract: Die durch Addition der Diazoalkane (II) an den Methoxymethylenmalonester (I) zugänglichen Pyrazoline (IIIa)‐(IIIc) und (IIIe) liefern bei der Thermolyse infolge Wasserstoff‐Wanderung bzw. Migration der Methoxygruppe die Methylenmalonester (IV) bzw. (V).

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