A number of research reports emerged recently describing the outcome of boron-doped diamond (BDD) as the unique electrode material in electrochemistry [1,2]. Such interest has resulted from the wide spread use of this material in electrochemical systems, for e-g., electroanalysis [3][4][5], electrocatalysis [6,7], waste-water treatment [8,9] and electrosynthesis [10]. It is to be noted that several properties such as carbon-oxygen functionalities, hydrophobicities, microsturcture and different electronic properties have influenced their utility in the electrode kinetics and reaction mechanisms.