Chemischer Informationsdienst. Organische Chemie
 1971
DOI: 10.1002/chin.197113010
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ChemInform Abstract: EIN NEUES ORGANISCHES SILICIUM‐CYCLOPHAN UND SEIN RADIKAL‐ANION

Fred Wudl1,
Robert D. Allendoerfer2,
J. Demirgian3
et al.

Abstract: Die Reaktion der 1,4‐Dichlor‐ und 1,4‐Dihydroxy‐hexamethyl‐1,4‐disilacyclohexa‐2,5‐diene (I) und (II) in Gegenwart von Triäthylamin liefert neben polymeren Verbindungen das Silicium‐cyclophan (III), aus dem bei ‐80°C mit Kalium in 1,2‐Dimethoxyäthan ein grünes Radikal‐Anion dargestellt wird.

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