ChemInform Abstract: Electron Transfer in Reactions of Ketones with Organolithium Reagents. A 14C Kinetic Isotope Effect Probe.

Yamataka, Hiroshi; Fujimura, Naoya; Kawafuji, Yukie; Hanafusa, Terukiyo

doi:10.1002/chin.198744090

ChemInform

1987

DOI: 10.1002/chin.198744090

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ChemInform Abstract: Electron Transfer in Reactions of Ketones with Organolithium Reagents. A 14C Kinetic Isotope Effect Probe.

Hiroshi Yamataka¹,

Naoya Fujimura²,

Yukie Kawafuji³

et al.

Abstract: 090ChemInform Abstract With the exception of (Ib) the electron transfer is the rate-determining step in the title reaction of (I) with (II). For (Ib) and all reactions with Me2CuLi the recombination of the radical ion pair determines the rate of reaction.

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ChemInform Abstract: Electron Transfer in Reactions of Ketones with Organolithium Reagents. A 14C Kinetic Isotope Effect Probe.

Abstract: 090ChemInform Abstract With the exception of (Ib) the electron transfer is the rate-determining step in the title reaction of (I) with (II). For (Ib) and all reactions with Me2CuLi the recombination of the radical ion pair determines the rate of reaction.

Cited by 0 publications

References 1 publication

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