ChemInform Abstract: EQUILIBRIUM IN AQUEOUS POLYMOLYBDATE SOLUTIONS. NEW INTERPRETATION OF THE POTENTIOMETRIC DATA OF SASAKI AND SILLEN

Tytko, Karl‐Heinz; Baethe, G.; Hirschfeld, E. R.; Mehmke, K.; Stellhorn, D.

doi:10.1002/chin.198348020

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2006

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“…The primary products by precipitation of Mo‐oxide are a mixture of molybdenum oxide hydrates, of hexagonal MoO 3 and of a family of supramolecular oxo‐clusters (Tytko et al ., 1983; Müller et al ., 2002). Recently, we have studied the conditions and selection mechanisms that allow control of the species obtained by aqueous precipitation (Hamid et al ., 2003).…”

Section: Introductionmentioning

confidence: 99%

Characterization of nanostructured binary molybdenum oxide catalyst precursors for propene oxidation

Wagner

Othman

Hamid

et al. 2006

Journal of Microscopy

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Summary High‐resolution transmission electron microscopy characterization of molybdenum oxide catalyst precursors is carried out for a better understanding of the mechanisms leading to the active catalytic material. The precipitated material consists of both large‐unit cell crystals and randomly orientated clusters on a 3–5 nm scale. The crystalline clusters are embedded in non‐crystalline material, preventing the formation of large well‐defined inactive orthorhombic MoO3 crystals during activation of the catalyst material.

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Section: Introductionmentioning

confidence: 99%