ChemInform Abstract: Facile Synthesis of Various 1‐Azabicyclo[n.4.0]alkanes via Beckmann Rearrangement/Allylsilane Cyclization.

Abstract

Multi-membered N-heterocycles R 0690Facile Synthesis of Various 1-Azabicyclo[n.4.0]alkanes via Beckmann Rearrangement/Allylsilane Cyclization. -A versatile and useful method for the synthesis of the title compounds proceeds via a sequence which includes organoaluminum-promoted Beckmann rearrangement of oxime mesylate (I), allylation and Mannich reaction. -(KANG*, K.-T.; SUNG, T. M.; JUNG, H. C.; LEE, J. G.; Bull. Korean Chem. Soc.