ChemInform Abstract: FLUORINE DERIVATIVES OF ADAMANTANE. IX. POLYHALOADAMANTANONES

Abstract

Die geminalen Adamantandifluoride (I) und (III) werden durch BBr3 in die entsprechenden geminalen Dibromide (II) bzw. (IV) übergeführt.

Reactions of adamantanes in electrophilic media

“…No isomerisation of the reaction product was also observed in the reaction of 2,2,5,7-tetrafluoroadamantane with BBr 3 . 86 1-Hydroxyadamantane (4) or its nitrate 12 are widely used as starting compounds in the synthesis of halogenoadamantanes. Thus 1-fluoroadamantane (33) was obtained by the reaction of 1hydroxyadamantane (4) with boron trifluoride diethyl etherate.…”