ChemInform Abstract: FORMATION OF 3,5‐DIOCTYL‐1,2,4‐DIOXAZOLE IN THE OZONATION OF 1‐DECENE IN THE PRESENCE OF AMMONIA

Filina, G. G.; Bortyan, T. A.; Menyailo, A. T.; Pospelov, M. V.

doi:10.1002/chin.198030246

Cited by 2 publications

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“…The main primary peroxide products of olefin ozonolysis in the presence of ammonia and amines are α-aminohydroperoxides118 [52]. Such peroxides were obtained as intermediate products in the ozonolysis of cyclopentadiene in anhydrous ammonia.…”

Section: Transformations Of Peroxide Products Of Olefins Ozonolysismentioning

confidence: 99%

“…By passing the ozone-oxygen mixture through a homogeneous mixture of 1-nonene with aqueous ammonia and acetone at -70°C in 86% yield colorless crystals, mp 60°C, were obtained, relatively stable at room temperature. They were identifi ed by NMR and IR spectroscopy as a symmetric ammozonide, 3,5-dioctyl-1,2,4-dioxazole 119 that apparently formed by the reaction of the intermediate peroxide compound with ammonia [52]. Formerly this type compounds were obtained by the reaction of aldehydes or ketones with hydrogen peroxide and ammonia.…”

Section: Transformations Of Peroxide Products Of Olefins Ozonolysismentioning

confidence: 99%

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Transformations of peroxide products of olefins ozonolysis

et al. 2010

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Section: Transformations Of Peroxide Products Of Olefins Ozonolysismentioning

confidence: 99%

Section: Transformations Of Peroxide Products Of Olefins Ozonolysismentioning

confidence: 99%

Transformations of peroxide products of olefins ozonolysis

et al. 2010

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Cyclic and Acyclic Azaperoxides

Makhmudiyarova

Ибрагимов

2019

BJSTR

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the fact that many natural compounds (verruculogen, dioxetanone) and antimalarial agents (RKA182 and OZ439) contain aza-peroxy moieties in the molecules. The extensive biological activity of nitrogen-containing peroxides promoted active research on the development of synthetic routes to new classes of acyclic and cyclic amino-peroxides.It is noteworthy that a compound containing both a nitrogen atom and a peroxide group in the molecule was first mentioned in the world literature back 1900 [1]. Despite more than a 100year history, amino-peroxides remain poorly studied because of complicated synthesis and small number of available preparation methods. In view of the high practical significance of fundamental and applied research dealing with the synthesis and use of amino-peroxides and extensive interest of researchers in this promising and intriguing field of chemistry, in the present review, we attempted to give a critical account of the achievements of both foreign and Russian researchers engaged in the synthesis and studies of the properties of three-, four-, five-, six-, and eight-membered cyclic and acyclic amino-peroxides with the goal of integrating published results. Three-Membered Aza-PeroxidesThe simplest cyclic peroxide derivatives are composed of a 3-membered ring consisting of one nitrogen and two oxygen atoms. These dioxaziridine rings can be formed both from nitro compounds [RN (O) O] and from nitroso O-oxides (RNOO) (Scheme 1). Dioxaziridines 1 (aza-dioxiranes) have not been isolated in a pure state, but have been identified as unstable intermediates in solutions in 2-methyltetrahydrofuran at 77 K [2] or acetonitrile at 298 K [3].

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ChemInform Abstract: FORMATION OF 3,5‐DIOCTYL‐1,2,4‐DIOXAZOLE IN THE OZONATION OF 1‐DECENE IN THE PRESENCE OF AMMONIA

Cited by 2 publications

References 0 publications

Transformations of peroxide products of olefins ozonolysis

Transformations of peroxide products of olefins ozonolysis

Cyclic and Acyclic Azaperoxides

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