ChemInform
 2013
DOI: 10.1002/chin.201350107
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ChemInform Abstract: Formation of Tetrahydrofurans via a 5‐endo‐tet Cyclization of Aziridines — Synthesis of (—)‐Pachastrissamine.

Chen-Wei Lin
1
,
Sin‐Wei Liu
2
,
Duen Ren Hou
3

Abstract: The 5‐endo‐tet cyclization/ring opening of aziridine (I) proceeds smoothly in the presence of HF/MeCN to afford tetrahydrofuran (II), which in turn is further elaborated to ent‐(‐)‐pachastrissamine (IV).

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