ChemInform Abstract: Gold‐Catalyzed Synthesis of Carbon‐Bridged Medium‐Sized Rings

Barabé, Francis; Bétournay, Geneviève; Bellavance, Gabriel; Barriault, Louis

doi:10.1002/chin.201004053

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2017

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“…To address this issue, we imagined a regioselective 6‐endo dig Au(I)‐catalyzed carbocyclization of silylenol ether 12 (Scheme ) . One can hypothesized that upon coordination of the gold(I) complex, the intermediate 13 could cyclize via three specific pathways.…”

Section: Methodsmentioning

confidence: 99%

Development of New Gold (I)‐Catalyzed Carbocyclizations and their Applications in the Synthesis of Natural Products

McGee

Brousseau

Barriault

2017

Israel Journal of Chemistry

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For many years, gold was considered inactive to catalyze organic transformations. In the last two decades, gold(I/III) complexes have emerged as efficient catalyst for the formation of C−O, C−N and C−C bonds. In particular, monomeric organogold complexes whose binding affinity for alkenes, allenes and alkynes opened new directions in organic synthesis. More recently, dimeric gold species were used as photocatalyst in light‐enabling processes. Taking advantage of the gold unique reactivity, we describe the development of novel transformations catalyzed by gold and their applications in the synthesis of natural products.

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Section: Methodsmentioning

confidence: 99%