ChemInform Abstract: HYDRAZINE ‐ ROCKET FUEL TO SYNTHETIC TOOL

Schiessl, Henry W.

doi:10.1002/chin.198115104

Cited by 4 publications

(2 citation statements)

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“…The transient decomposition of liquid hydrazine in a space vehicle forms a hightemperature gas mixture ejecting from the nozzle of the thruster to change the flight orbit or to regulate the flight attitude of the space vehicle. 180 The use of hydrazine in satellite attitude control is due to the low activation energy of its decomposition and the high exothermicity of this reaction. 179 Hydrazine, both in alkaline and in acid solutions, is capable of undergoing thermal decomposition.…”

Section: Decomposition Of Hydrazinementioning

confidence: 99%

Create a Consortium and Develop Premium Carbon Products from Coal

Rusinko¹,

Andrésen²,

Hill³

et al. 2006

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The objective of these projects was to investigate alternative technologies for non-fuel uses of coal. Special emphasis was placed on developing premium carbon products from coal-derived feedstocks. A total of 14 projects, which are the 2003 Research Projects, are reported herein. These projects were categorized into three overall objectives. They are:(1) To explore new applications for the use of anthracite in order to improve its marketability; (2) To effectively minimize environmental damage caused by mercury emissions, CO 2 emissions, and coal impounds; and (3) To continue to increase our understanding of coal properties and establish coal usage in non-fuel industries.Research was completed in laboratories throughout the United States. Most research was performed on a bench-scale level with the intent of scaling up if preliminary tests proved successful.These projects resulted in many potential applications for coal-derived feedstocks. These include:• Use of anthracite as a sorbent to capture CO 2 emissions • Use of anthracite-based carbon as a catalyst • Use of processed anthracite in carbon electrodes and carbon black • Use of raw coal refuse for producing activated carbon • Reusable PACs to recycle captured mercury • Use of combustion and gasification chars to capture mercury from coal-fired power plants • Development of a synthetic coal tar enamel • Use of alternative binder pitches in aluminum anodes • Use of Solvent Extracted Carbon Ore (SECO) to fuel a carbon fuel cell • Production of a low cost coal-derived turbostratic carbon powder for structural applications • Production of high-value carbon fibers and foams via the co-processing of a low-cost coal extract pitch with well-dispersed carbon nanotubes • Use of carbon from fly ash as metallurgical carbon • Production of bulk carbon fiber for concrete reinforcement • Characterizing coal solvent extraction processes Although some of the projects funded did not meet their original goals, the overall objectives of the CPCPC were completed as many new applications for coal-derived feedstocks have been researched. Future research in many of these areas is necessary before implementation into industry. Potential Application for Exfoliated Anthracite: Filler in CathodesThe Pennsylvania State University -Subcontract # 2486-TPSU-DOE-0350…………….19 Use of Coal Gasification and Combustion Chars for Mercury CaptureThe Pennsylvania State University -Subcontract # 2482-TPSU-DOE-0350…………….46 Binding Efficiency of Coal-Derived Binders Towards Anode ButtsThe EXECUTIVE SUMMARYThe objective of these projects was to investigate alternative technologies for non-fuel uses of coal. Special emphasis was placed on developing premium carbon products from coal-derived feedstocks. A total of 14 projects, which are the 2003 Research Projects, are reported herein. These projects were categorized into three overall objectives. They are:(1) To explore new applications for the use of anthracite in order to improve its marketability; (2) To effectively minimize environmenta...

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Section: Decomposition Of Hydrazinementioning

confidence: 99%

Create a Consortium and Develop Premium Carbon Products from Coal

Rusinko¹,

Andrésen²,

Hill³

et al. 2006

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“…The use of hydrazine hydrate as a hydrogen donor for unsaturated organic compounds has been known for decades. , There are numerous experimentally and theoretically based arguments indicating that the active hydrogen transfer reagent is not hydrazine, but diimide (NHNH). , The most widespread application has been found in the saturation of olefins or multiple carbon–carbon bonds . Also, nitro groups have been reduced to the corresponding amines but only in the presence of metal catalysts, such as Pd, Ni, and Ru. ,, Aldehydes and ketones can be converted into alkanes by the use of hydrazine under harsh Wolff–Kishner conditions (high temperature, solid KOH), , where the corresponding alcohol has been reported as a byproduct . Although hydrazine is considered as a reducing agent, the reduction of aldehydes or ketones to the corresponding alcohols has largely been considered unfeasible due to the rapid condensation reactions .…”

Section: Introductionmentioning

confidence: 99%

Reduction Over Condensation of Carbonyl Compounds Through a Transient Hemiaminal Intermediate Using Hydrazine

et al. 2020

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Reduction of carbonyl moieties to the corresponding alcohol using simply hydrazine hydrate has been considerably unfeasible until now due to the wellknown condensation reaction. However, herein, we report that using an excess of 20fold equivalents, the reduction proceeds in excellent yields. 1 H NMR study of the reaction and density functional theory (DFT) calculations indicate that the final fate of the hemiaminal intermediate is crucial to obtain the alcohol or the hydrazone.

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Microdetermination of aliphatic diamines and polyamines with cupric ion

Selig

1982

Microchemical Journal

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ChemInform Abstract: HYDRAZINE ‐ ROCKET FUEL TO SYNTHETIC TOOL

Cited by 4 publications

References 0 publications

Create a Consortium and Develop Premium Carbon Products from Coal

Create a Consortium and Develop Premium Carbon Products from Coal

Reduction Over Condensation of Carbonyl Compounds Through a Transient Hemiaminal Intermediate Using Hydrazine

Microdetermination of aliphatic diamines and polyamines with cupric ion

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