ChemInform Abstract: HYDROSILYLATION. RECENT ACHIEVEMENTS

Lukevics, É.; Belyakova, Z. V.; Pomerantseva, M. G.; Воронков, М. Г.

doi:10.1002/chin.197828338

Cited by 16 publications

(15 citation statements)

References 1 publication

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“…

agrees with that reported earlier.14 Preparation of 3a,4,4a,4,8,. To a solution of 47 g (0.27 mol) of dicyclopentadienyldimethylmethane in 500 mL of THF at -20 °C, 27 mL of 2.0 N hexane solution of n-butyllithium (0.54 mol) was added under stirring at -20 °C.

…”

supporting

confidence: 92%

Low quantum yields of chromium hexacarbonyl substitution in fluorocarbon solvent: evidence that metal-fluorocarbon interactions are very weak

Nayak¹,

Burkey²

1991

Organometallics

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“…

…”

supporting

confidence: 92%

Low quantum yields of chromium hexacarbonyl substitution in fluorocarbon solvent: evidence that metal-fluorocarbon interactions are very weak

Nayak¹,

Burkey²

1991

Organometallics

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“…Synthetic applications of dehydrocondensation of silanes with hydroxy-containing organic compounds and the mechanism of this reaction have been adequately surveyed in the reviews. 1, 9 ± 14 Of more recent investigations, studies on alcoholysis of mono-, di-and trisubstituted silanes with saturated and unsaturated primary and secondary alcohols and diols in the presence of complexes of copper {[Ph 3 PCuH] 6 }, 15 titanium 16 and manganese {[Mn(CO) 4 Br] 2 } 17 as well as in the presence of soluble platinum, palladium, nickel, ruthenium and rhodium complexes fixed on silica gel, 18 ± 20 and studies on alcoholysis of disilanes in the presence of tetrabutylammonium fluoride 21 are worthy of note.…”

Section: Methodsmentioning

confidence: 99%

Dehydrocondensation of organylsilanes giving Si–Si bonds

Pukhnarevich¹,

Воронков²,

Kopylova³

2000

Russ. Chem. Rev.

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Particle trapping effects on stimulated Brillouin and Raman scattering have been investigated. A time and space dependent model assumes a Maxwellian plasma which is taken to be homogeneous in the interaction region. Ion trapping has a rather weak effect on stimulated Brillouin scattering and large reflectivities are obtained even in strong trapping regime. Stimulated Raman scattering is considerably reduced by electron trapping. Typically 15-20 times larger laser intensities are required to obtain same reflectivity levels than without trapping.

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“…mixture was further treated with di-tert-butyl dicarbonate in methylene chloride at room temperature to yield 11-N-(tert-butoxycarbonyl)-aminoundecene. Hydrosilylation (Lukevics et al, 1977;Wasserman et al, 1989) via reaction with triethoxysilane and hydrogen hexachloroplatinate (IV) hydrate for 48 h at 93°C yielded, upon distillation, the precursor 11-N-(tert-butoxycarbonyl)-aminoundecyltriethoxysilane. Satisfactory IR, 500-MHz 1H NMR, and 62.5-MHz "3C NMR spectra were obtained for this compound.…”

Section: Methodsmentioning

confidence: 99%

Vectorially oriented membrane protein monolayers: profile structures via x-ray interferometry/holography

Chupa

McCauley

Strongin

et al. 1994

Biophysical Journal

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X-ray interferometry/holography was applied to meridional x-ray diffraction data to determine uniquely the profile structures of a single monolayer of an integral membrane protein and a peripheral membrane protein, each tethered to the surface of a solid inorganic substrate. Bifunctional, organic self-assembled monolayers (SAMs) were utilized to tether the proteins to the surface of Ge/Si multilayer substrates, fabricated by molecular beam epitaxy, to facilitate the interferometric/holographic x-ray structure determination. The peripheral membrane protein yeast cytochrome c was covalently tethered to the surface of a sulfhydryl-terminated 11-siloxyundecanethiol SAM via a disulfide linkage with residue 102. The detergent-solubilized, photosynthetic reaction center integral membrane protein was electrostatically tethered to the surface of an analogous amine-terminated SAM. Optical absorption measurements performed on these two tethered protein monolayer systems were consistent with the x-ray diffraction results indicating the reversible formation of densely packed single monolayers of each fully functional membrane protein on the surface of the respective SAM. The importance of utilizing the organic self-assembled monolayers (as opposed to Langmuir-Blodgett) lies in their ability to tether specifically both soluble peripheral membrane proteins and detergent-solubilized integral membrane proteins. The vectorial orientations of the cytochrome c and the reaction center molecules were readily distinguishable in the profile structure of each monolayer at a spatial resolution of 7 A.

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ChemInform Abstract: HYDROSILYLATION. RECENT ACHIEVEMENTS

Cited by 16 publications

References 1 publication

Low quantum yields of chromium hexacarbonyl substitution in fluorocarbon solvent: evidence that metal-fluorocarbon interactions are very weak

Low quantum yields of chromium hexacarbonyl substitution in fluorocarbon solvent: evidence that metal-fluorocarbon interactions are very weak

Dehydrocondensation of organylsilanes giving Si–Si bonds

Vectorially oriented membrane protein monolayers: profile structures via x-ray interferometry/holography

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