ChemInform Abstract: Influence of the Complexation on the Reactivity of Halogen Nitrates.

Gaude, Didier; Gellon, Gisèle; Goaller, R. Le; Pierre, Jean‐Louis

doi:10.1002/chin.198926143

ChemInform

1989

DOI: 10.1002/chin.198926143

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ChemInform Abstract: Influence of the Complexation on the Reactivity of Halogen Nitrates.

Didier Gaude¹,

Gisèle Gellon²,

R. Le Goaller³

et al.

Abstract: The title nitrates, e.g. (VI), react with phenols to give halogenated and nitrated products.

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Influence de la complexation sur la réactivité de nitrates d'halogènes

Gaude¹,

Gellon²,

Goaller³

et al. 1989

Can. J. Chem.

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Iodine nitrate or bromine nitrate in acetonitrile or in chloroform react with a variety of phenolic substrates to form both halogenated and nitrated products. In the presence of strong complexing agents of halonium ions, no reaction occurs, while in the presence of pyridine or triethylamine, only halogenated phenols exhibiting a strong ortho-directing effect of the phenolic function are produced. Keywords: phenols, iodine nitrate, bromine nitrate, halogenation, nitration.

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Influence de la complexation sur la réactivité de nitrates d'halogènes

Gaude¹,

Gellon²,

Goaller³

et al. 1989

Can. J. Chem.

View full text Add to dashboard Cite

show abstract

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ChemInform Abstract: Influence of the Complexation on the Reactivity of Halogen Nitrates.

Abstract: The title nitrates, e.g. (VI), react with phenols to give halogenated and nitrated products.

Cited by 1 publication

References 1 publication

Influence de la complexation sur la réactivité de nitrates d'halogènes

Influence de la complexation sur la réactivité de nitrates d'halogènes

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