1986
DOI: 10.1002/chin.198611164
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ChemInform Abstract: l‐Trifluoromethylvinyl Alkyl(aryl) Sulfones.

Abstract: Durch Reaktion des Sulfenylchlorids (I) mit den Alkenen (II) werden die Sulfide (III) erhalten, die durch Behandeln mit NEt3 unter HCl‐Abspaltung in die Vinylderivate (IV) übergehen.

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“…129 1,1,1-Trifluoroisopropenyl sulfides enter into the Diels ± Alder reaction with cyclopentadiene on heating to 100 8C being thus converted into mixtures of endo-and exo-adducts. 21,130 Cycloaddition of trifluoromethylthioethylene to 2,3-dimethylbuta-1,3-diene occurs under drastic conditions. 62…”
Section: Cycloadditionmentioning
confidence: 99%
“…129 1,1,1-Trifluoroisopropenyl sulfides enter into the Diels ± Alder reaction with cyclopentadiene on heating to 100 8C being thus converted into mixtures of endo-and exo-adducts. 21,130 Cycloaddition of trifluoromethylthioethylene to 2,3-dimethylbuta-1,3-diene occurs under drastic conditions. 62…”
Section: Cycloadditionmentioning
confidence: 99%