1996
DOI: 10.1002/chin.199601021
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ChemInform Abstract: Metal Clusters in Plasma Polymer Matrices: Gold Clusters.

Abstract: Metal Clusters in Plasma Polymer Matrices: Gold Clusters.-A novel deposition technique separating the metal cluster source from the plasma discharge region is developed and used for the preparation of gold clusters of 1.4-5.0 nm diameter within polymer matrices from vinyltrimethylsilane and tetraethoxysilane monomers. The polymer-entrapped gold clusters are characterized by HRTEM, XPS, FTIR spectroscopy, and UV/VIS spectrophotometry. This technique can also be applied for the preparation of e.g. Pd, Pt, and Ag… Show more

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“…Silver particles with a narrow size distribution have been produced upon reversible chemical transformation between metallic and oxide states in a titania matrix [14] and in a mesoporous silica which was grafted with hydrophobic -Si(CH 3 ) 3 groups at the pore surface [15].…”
Section: Introductionmentioning
confidence: 99%
“…Silver particles with a narrow size distribution have been produced upon reversible chemical transformation between metallic and oxide states in a titania matrix [14] and in a mesoporous silica which was grafted with hydrophobic -Si(CH 3 ) 3 groups at the pore surface [15].…”
Section: Introductionmentioning
confidence: 99%