ChemInform Abstract: N‐Pyrrolidine‐Based α/β‐Peptides Incorporating ABOC, a Constrained Bicyclic β‐Amino Acid, for Asymmetric Aldol Reaction Catalysis.

Abstract

Catalytic properties of 15 N‐pyrrolidine‐based α,β‐peptides incorporating a constrained 2‐aminobicyclo[2.2.2]octane carboxylic acid (ABOC) are evaluated in the asymmetric aldol reaction from acetone and some p‐substituted benzaldehydes.