ChemInform Abstract: Neutron and X‐Ray Diffraction Studies on the High Temperature Phase of Mn3(VO4)2, the New Isostructural Compound NaMn4(VO4)3 and Their Mixed Crystals NaxMn4.5‐x/2(VO4)3 (0 ≤ x ≤ 1).
Abstract:NaMn4(VO4)3 and NaxMn4.5‐x/2(VO4)3 (0 ≤ x ≤ 1) are synthesized by solid state reaction of stoichiometric mixtures of Na2CO3, MnO, and V2O5 (Pt boat, argon stream, 900 °C, 20 h).
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