ChemInform Abstract: New Phosphine—Imine Ligands Derived from D‐Gluco‐ and D‐Galactosamine in Pd‐Catalyzed Asymmetric Allylic Alkylation.

Abstract

New Phosphine-Imine Ligands Derived from D-Gluco-and D-Galactosamine in Pd-Catalyzed Asymmetric Allylic Alkylation. -It is demonstrated that the carbohydrate based new phosphine-imine (DGA) is an efficient ligand for the asymmetric allylic alkylation of acetate (I) with malonates. -(SZULC, I.; KOLODZIUK, R.; KRYCZKA, B.; ZAWISZA*, A.; Tetrahedron Lett. 56 (2015) 33, 4740-4743, http://dx.