ChemInform Abstract: Nickel‐Catalyzed Carbonylative Cycloaddition of Allyl Halides and Alkenes.

Abstract

Bridged compounds Q 0060Nickel-Catalyzed Carbonylative Cycloaddition of Allyl Halides and Alkenes. -The reaction between norbornenes and allyl halides uses cheap reagents and catalysts to provide tricyclic ketones and norbornane carboxylic acid derivatives as the major products. The ratio of the two major products can be tuned by addition of water. -(DEL MORAL, D.; MORETO, J. M.; MOLINS, E.; RICART*, S.; Tetrahedron Lett. 49 (2008) 49, 6947-6950; Lab. Catal. Homogenia, Inst. Cienc. Mater., CSIC, Bellaterra, E-08193 Barcelona, Spain; Eng.) -Mais 11-072