ChemInform Abstract: Nitrosylation of Hexafluoridotechnetate(IV).

Abstract

Nitrosylation of Hexafluoridotechnetate(IV). -[Tc(NO)(NH3)4F]4[TcF6][HF2]2 is obtained in almost quantitative yield by reaction of K 2[TcF6] with acetohydroxamic acid (Ac-NH-OH) in aqueous HF solution. The compound crystallizes in the monoclinic space group C2/m with Z = 2. The structure consists of four distorted octahedral [Tc(NO)(NH 3)4F] + cations, one [TcF6] 2-, and two [HF2]anions. -(BALASEKARAN, S. M.; MOLSKI, M.; HAGENBACH, A.; ABRAM*, U.; Z. Anorg. Allg. Chem. 639 (2013) 5, 672-675, http://dx.doi.org/10.1002/zaac.201300105 ; Inst. Chem.