ChemInform Abstract: NONCYCLIC CROWN‐TYPE POLYETHERS, PYRIDINOPHANE CRYPTANDS, AND THEIR ALKALI METAL ION COMPLEXES‐ SYNTHESIS, COMPLEX STABILITY, AND KINETICS

Tuemmler, Burkhard; Maaß, G.; Weber, Eva; Wehner, W.; Voegtle, F.

doi:10.1002/chin.197741331

Cited by 1 publication

(1 citation statement)

References 1 publication

Supporting

Mentioning

Contrasting

Order By: Relevance

“…Cryptands (Dietrich et al, 1969) are well known for their ability to bind cations, anions, and neutral molecules (Taylor et al, 2012). Macrobicyclic diamides have been used as hosts for cations (Hourdakis & Popov, 1977;Tuemmler et al, 1977;Buschmann, 1986;Rodopoulos et al, 2001;Meyer et al, 2004;Wanichacheva et al, 2006) and anions (Bernier et al, 2009). Tertiary amides have also been shown to form metal complexes (Niklas et al, 2004;Schickaneder et al, 2006;Jakob et al, 2015).…”

Section: Introductionmentioning

confidence: 99%

Synthesis and structures of three benzoannelated macrobicyclic diamides

Smith

Taylor

2022

Acta Crystallogr C

View full text Add to dashboard Cite

We report the synthesis and structures of 9,10,20,21-tetrahydro-5,14-(ethanooxyethano)dibenzo[e,q][1,4,10,13,7,16]tetraoxadiazacyclooctadecine-6,13-dione [systematic name: 8,11,21,24,29-pentaoxa-1,18-diazatetracyclo[16.8.5.02,7.012,17]hentriaconta-2,4,6,12(17),13,15-hexaene-19,26-dione C24H28N2O8, I], 6,7,9,10,12,13,20,21-octahydro-5,14-(ethanooxyethano)dibenzo[e,q][1,4,10,13,7,16]tetraoxadiazacyclooctadecine-23,27-dione (8,11,21,24,29-pentaoxa-1,18-diazatetracyclo[16.8.5.02,7.012,17]hentriaconta-2,4,6,12,14,16-hexaene-27,31-dione; C24H28N2O7, II), and 9,10,20,21-tetrahydro-5,14-(ethanooxyethanooxyethano)dibenzo[e,q][1,4,10,13,7,16]tetraoxadiazacyclooctadecine-6,13-dione [8,11,21,24,29,32-hexaoxa-1,18-diazatetracyclo[16.8.8.02,7.012,17]tetratriaconta-2,4,6,12(17),13,15-hexaene-19,26-dione; C26H32N2O7, III]. All three compounds are made up of two tertiary diamides and are composed of two 15-membered rings with N2O3 donor sets and one 18-membered ring with an N2O4 donor set (compounds I and II) or three 18-membered rings with N2O4 donor sets (compound III). The solid-state structures of compounds I and II show little effects from the movement of the amide groups. However, compound III has a larger cavity and a different orientation of donor atoms in comparison to compounds I and II.

show abstract