ChemInform Abstract: Organo‐Arsenic Compounds with an As=N Bond. Part 9. Synthesis, Properties, and Structure of Diaminoarsonium Chlorides.

Abstract

ChemInform Abstract The diaminoarsonium chloride (III), prepared from the trichloroarsorane (I) and tert-butylamine (II), is hydrolyzed to produce (II), its hydrochloride (V), and diphenylarsinic acid (IV). (X-ray analysis of (III): monoclinic, space group P21/c, Z=4).

Hydrogen-Bond Distances to Halide Ions in Organic and Organometallic Crystal Structures: Up-to-date Database Study

“…It is unfortunate that the data quantities do not reasonably allow such a subdivision for the strong AsÐOH and PÐOH donors. The crystal structure of the arsenic analog (Ph) 3 As + Ð OHÁ Á ÁCl À contains two symmetry-independent formula units, one of which forms the second shortest hydrogen bond to Cl À in the data set: HÁ Á ÁCl À = 1.87 A Ê , OÁ Á ÁCl À = 2.85 A Ê and angle at H = 171 (Kokorev et al, 1987). The crystal structure of the arsenic analog (Ph) 3 As + Ð OHÁ Á ÁCl À contains two symmetry-independent formula units, one of which forms the second shortest hydrogen bond to Cl À in the data set: HÁ Á ÁCl À = 1.87 A Ê , OÁ Á ÁCl À = 2.85 A Ê and angle at H = 171 (Kokorev et al, 1987).…”