ChemInform Abstract: Organocatalytic Asymmetric Fluorination/Semipinacol Rearrangement: An Efficient Approach to Chiral β‐Fluoroketones.

Abstract

Chiral β-Fluoroketones. -Organocatalysts with dihydroquinidine and dihydroquinine moieties provide access to both enantiomers of asymmetrically substituted tetrahydropyrans (II) and tetrahydrofurans (IV). -(CHEN, Z.-M.; YANG, B.-M.; CHEN, Z.-H.; ZHANG, Q.-W.; WANG, M.; TU*, Y.-Q.; Chem. Eur. J. 18 (2012) 41, 12950-12954, http://dx.