ChemInform Abstract: Palladium‐Catalyzed Decarboxylative Intramolecular Aziridination from 4H‐Isoxazol‐5‐ones Leading to 1‐Azabicyclo[3.1.0]hex‐2‐enes.

Abstract

A decarboxylative intramolecular aziridination reaction of alkene‐tethered isoxazol‐5‐ones with a palladium/phosphine catalyst gives N‐fused bicyclic aziridines which readily react with various reagents to afford ring‐opened pyrroline derivatives.