ChemInform
 2016
DOI: 10.1002/chin.201628115
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ChemInform Abstract: Palladium(II)‐Catalyzed Annulation of Alkynes with 2‐(Cyanomethyl)phenylboronates Leading to 3,4‐Disubstituted 2‐Naphthalenamines.

Hirokazu Tsukamoto
1
,
Taishi Ikeda
2
,
Takayuki Doi
3

Abstract: This reaction proceeds through transmetalation of the palladium(II) complex with boronates and alkyne insertion followed by nucleophilic addition of the generated alkenylpalladium(II) species to the cyano group.

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