ChemInform Abstract: PRODUCTS OF THE EPOXIDATION OF DICYCLOPENTADIENE BY MONOPERPHTHALIC ACID

Abstract

endo‐ Dicyclopentadien (I) reagiert mit Monoperphthalsäure zu den Epoxiden (II)‐(IV).

Curing kinetics and thermal property characterization of a bisphenol-S epoxy resin and DDS system

“…Because of the introduction of sulfonyl groups into the backbone of epoxy resins, the improved resins based on bisphenol-S (BPS) are considered worthy of further study in terms of their good thermal stability, chemical resistance, mechanical properties and modi®cation compared with that of the bisphenol-A epoxy resin (BPAER). 1,2 The cure process and the thermal properties of this thermosetting material affect its macroscopic properties, which govern its end-use performance. The bisphenol-S epoxy resin (BPSER), synthesized from bisphenol-S and epichlorohydrin was described for the ®rst time by Beavers in 1953.…”

Kinetics and mechanism of esterification of epoxy resin in presence of triphenylphosphine

“…Amines have been important catalysts for the esterification of epoxides for many years. The kinetics of addition esterification of monoepoxy 9–11 and diepoxy compounds 12, 13 with acids in presence of quinoline 9, trihexylamine 10, dimethylbenzylamine 11, N , N ‐dimethyl toluidine 12, and pyridine 13 has been studied and it showed variations in reaction rate, order, and mechanism primarily due to the nature of catalyst. The use of catalysts other than amines such as triphenylphosphine 14, 15, Sb(ph) 3 16, chromium diisopropylsalicylate 17 has also been reported in literature.…”

Kinetics and mechanism of esterification of epoxy resin with methacrylic acid in the presence of tertiary amines

“…14,15 An investigation of the reaction kinetics is needed for the selection of proper conditions to proceed the reaction in desired direction. The kinetics of addition esterification of monoepoxy compounds with benzoic acid, 16 pentanoic acid, 17 and caproic acid 18 in the presence of tertiary amines has been investigated, and it showed variations in reaction rate, order, and mechanism, primarily due to nature of the catalyst. However, the effect of catalyst on esterification kinetics of diepoxy compounds has rarely been considered.…”