“…[ N ] plot). In the other reactions k, was negligible compared with the second term of equation(2). The k, values found for the solvolysis of (5) were 103k, = 1.4,2.0,3.6,6.1, and 10.0 s-' at 25,30,35,40, and 45 "C, respectively.…”
The reactions of S-ethoxycarbonyl O-ethyl dithiocarbonate (1 ), bis(ethoxythiocarbony1) sulphide (4), and bis(ethoxycarbony1) sulphide (5) with pyrrolidine, piperidine, and morpholine in 95% aqueous ethanol have been subjected to kinetic study. The rate equation found for all the reactions is
“…[ N ] plot). In the other reactions k, was negligible compared with the second term of equation(2). The k, values found for the solvolysis of (5) were 103k, = 1.4,2.0,3.6,6.1, and 10.0 s-' at 25,30,35,40, and 45 "C, respectively.…”
The reactions of S-ethoxycarbonyl O-ethyl dithiocarbonate (1 ), bis(ethoxythiocarbony1) sulphide (4), and bis(ethoxycarbony1) sulphide (5) with pyrrolidine, piperidine, and morpholine in 95% aqueous ethanol have been subjected to kinetic study. The rate equation found for all the reactions is
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