ChemInform Abstract: Rapid Synthesis of Aziridine Derivatives over Bentonite in “Dry Media”.

Abstract

Rapid Synthesis of Aziridine Derivatives over Bentonite in "Dry Media".-Functionalized aziridine derivatives are synthesized from dibromo compounds (I) and primary aliphatic amines in the absence of solvent over bentonite as solid support. Microwave irradiation or classical heating accelerates the aziridine formation. -(SAOUDI, A.; HAMELIN, J.; BENHAOUA, H.;

Copper-Exchanged Bentonite: A Reusable Catalysis for the Formation of Alkoxycarbonyl Nitrile Ylides under Microwave Irradiation

“…Sometimes long reaction times and tedious work-up are necessary. In the course of our studies related to the use of inorganic solid supports in heterocyclic synthesis, 7 we have extended this work to modified bentonite. Here, we report the catalytic effect of copper exchanged bentonite (BCu) in the decomposition of ethyl diazoacetate (EDA) in the presence of various nitriles as a suitable route to alkoxycarbonyl-substituted nitrile ylides.…”