ChemInform Abstract: Reaction of Alcohols with Bromine.

Baklan, V. F.; Khil'chevskii, A. N.; D'yakovskaya, V. M.; Sologub, L. S.; Kukhar, V. P.

doi:10.1002/chin.199417047

Cited by 6 publications

(7 citation statements)

References 0 publications

Supporting

Mentioning

Contrasting

Order By: Relevance

“…512 Interestingly, the hydroxylation of adamantane with bromine water afforded a 95% yield of 1hydroxyadamantane via hydrolysis of the intermediate bromide. 513 However, bromination of 1-hydroxyadamantane with bromine afforded 1-bromoadamantane in 90% yield.…”

Section: Saldabols Et Al Carried Out Bromination Of Imidazothiazolesmentioning

confidence: 99%

Use of Bromine and Bromo-Organic Compounds in Organic Synthesis

2016

View full text Add to dashboard Cite

Bromination is one of the most important transformations in organic synthesis and can be carried out using bromine and many other bromo compounds. Use of molecular bromine in organic synthesis is well-known. However, due to the hazardous nature of bromine, enormous growth has been witnessed in the past several decades for the development of solid bromine carriers. This review outlines the use of bromine and different bromo-organic compounds in organic synthesis. The applications of bromine, a total of 107 bromo-organic compounds, 11 other brominating agents, and a few natural bromine sources were incorporated. The scope of these reagents for various organic transformations such as bromination, cohalogenation, oxidation, cyclization, ring-opening reactions, substitution, rearrangement, hydrolysis, catalysis, etc. has been described briefly to highlight important aspects of the bromo-organic compounds in organic synthesis.

show abstract

Section: Saldabols Et Al Carried Out Bromination Of Imidazothiazolesmentioning

confidence: 99%

Use of Bromine and Bromo-Organic Compounds in Organic Synthesis

2016

View full text Add to dashboard Cite

show abstract

“…(10 mm) [7]. 13 C NMR spectrum, δ C , ppm: 22.52 (CH 3 ), 30.76 (C 3 , C 5 , C 7 ), 36.17 (C 4 , C 6 , C 9 ), 41.28 (C 2 , C 8 , C 10 ), 80.12 (C 1 ), 170.19 (C=O).…”

Section: -Adamantyl Acetate (Iii) Sublimes At 97°cmentioning

confidence: 99%

Synthesis of 1-acetyladamantane by reaction of 1-bromoadamantane with vinyl acetate and ethylidene diacetate catalyzed by Mn2(CO)10

2010

View full text Add to dashboard Cite

show abstract

“…Adamantyl cation is generated therefrom by the action of concentrated sulfuric [4] or nitric acid [5], oleum [6], equimolar mixture of trifluoroacetic acid and boron trifluoride-diethyl ether complex [7], or liquid bromine [8]. These reagents are taken in a large excess with respect to 1-bromoadamantane (1), which complicates the isolation of target products [9].…”

mentioning

confidence: 99%