ChemInform Abstract: Reaction of Vinyl Selenides with Secondary Phosphines and Elemental Selenium: One‐Pot Selective Synthesis of a New Family of Diselenophosphinic Se‐Esters.

Artem’ev, Alexander V.; Чернышeва, Н. А.; Гусарова, Н. К.; Yas’ko, S. V.; Liao, Jian‐Hong; Liu, C. W.; Albanov, A. I.; Трофимов, Б. А.

doi:10.1002/chin.201444200

Search citation statements

Order By: Relevance

Paper Sections

Select...

Homopolyatomic Selenium Cations1

[Ticp2se51

Citation Types

Supporting

Mentioning

Contrasting

Year Published

2018

2019

Publication Types

Select...

Book1

Article1

Relationship

Self Cite0

Independent2

Authors

Journals

Cited by 2 publications

(2 citation statements)

References 4 publications

Supporting

Mentioning

Contrasting

Order By: Relevance

“…The known homopolyselenium cations include Se4 2+ , Se8 2+ , and Se10 2+ , but no applications of these species in synthesis have been reported. The interaction of elemental selenium with phosphines [64] is exemplified by the one-pot synthesis of diselenophosphinic selenoesters [65]. A more detailed discussion of the preparation and application of phosphorus-selenium reagents is presented in Chapter 5.…”

Section: Homopolyatomic Selenium Cationsmentioning

confidence: 99%

1. Introduction of selenium and tellurium into reaction systems

Laitinen¹,

Oilunkaniemi²,

Chivers³

2019

Selenium and Tellurium Reagents

View full text Add to dashboard Cite

show abstract

Section: Homopolyatomic Selenium Cationsmentioning

confidence: 99%

1. Introduction of selenium and tellurium into reaction systems

Laitinen¹,

Oilunkaniemi²,

Chivers³

2019

Selenium and Tellurium Reagents

View full text Add to dashboard Cite

show abstract

“…The interaction of elemental selenium with phosphines [64] is exemplified by the one-pot synthesis of diselenophosphinic selenoesters [65]. A more detailed discussion of the preparation and application of phosphorus-selenium reagents is presented in Chapter 5.…”

Section: [Ticp2se5mentioning

confidence: 99%

Introduction of selenium and tellurium into reaction systems

Laitinen

Oilunkaniemi

Chivers

2018

Physical Sciences Reviews

View full text Add to dashboard Cite

Abstract The introduction of selenium and tellurium into both organic and inorganic compounds frequently begins with the elements. This chapter provides an overview of the main reactivity of the hexagonal allotropes of selenium and tellurium, which are the most stable form of the elements under ambient conditions. While the two elements have very similar chemical properties, there are also notable differences. Upon reduction, both elements form mono- and poly-chalcogenides, which are useful nucleophilic reagents in several reactions. The elements also react with many main group compounds as well as with transition metal complexes. They also form homopolyatomic cations upon oxidation. Both selenium and tellurium react with Grignard reagents and organyllithium compounds affording organylchalcogenolates, which upon oxidation form dichalcogenides that are themselves useful reagents in organic synthetic chemistry as well as in materials applications. This chapter provides a short introduction to the various topics that will be developed further in the subsequent chapters of this book.

show abstract

ChemInform Abstract: Reaction of Vinyl Selenides with Secondary Phosphines and Elemental Selenium: One‐Pot Selective Synthesis of a New Family of Diselenophosphinic Se‐Esters.

Abstract: are prepared. A possible mechanism for the multicomponent one-pot reaction is given. -(ARTEM'EV, A. V.; CHERNYSHEVA, N. A.; GUSAROVA, N. K.; YAS'KO, S. V.; LIAO, J.-H.; LIU, C. W.; ALBANOV, A. I.; TROFIMOV*, B. A.; Heteroat. Chem. 25 (2014) 3, 135-139, http://dx.

Cited by 2 publications

References 4 publications

1. Introduction of selenium and tellurium into reaction systems

1. Introduction of selenium and tellurium into reaction systems

Introduction of selenium and tellurium into reaction systems

Contact Info

Product

Resources

About