ChemInform Abstract: Reaktion von Cyclopentadien-trans-dioxid mit Aminen.

Abstract

Die aus dem Monoepoxid (I) erhaltene Titelverbindung (II) wird mit den Aminen (III) umgesetzt.

The Reaction of 1,2:3,4‐Diepoxy‐2,3‐dimethylbutane with Nucleophiles

“…Independent reaction of the two epoxide moieties was usually found. In contrast to this, Kozlov et al [9] reported some years ago that trans-1,2:3,4-diepoxyc:yclopentane (1) reacted with secondary amines to give a product 4 with a central epoxy group which obviously arose from a 1,4-addition (Scheme 2). Besides 4, the expected 1,2-addition products 2 and 3 were observed.…”