ChemInform Abstract: Reductive Nitrosylation of Tetraoxometallates. Part 14. Generation and Proton Induced Disproportionation of the Re(NO)3+ Moiety. Synthesis, Characterization, and Electrochemistry of Novel Hydroxo‐ and Halogenonitrosyl Complexes of Rhenium.

Abstract

The IR and ESR spectra indicate that the complex (IV) have C4v symmetry and that the neutral complex (VI) also possesses axially symmetric structures containing the nitrogen atoms of the ligand in equatorial‐equatorial position.