Chemischer Informationsdienst
 1983
DOI: 10.1002/chin.198314137
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ChemInform Abstract: REDUCTONES AND TRICARBONYL COMPOUNDS. PART 30. ALKOXYCARBONYL‐ AND CARBOXYLATE‐GROUP MIGRATIONS IN THE BENZILIC ACID REARRANGEMENT OF ETHYL CYCLOPROPANE‐2,3‐DIOXOPROPIONATE

H. Dahn1,
Lê H. Dao2,
R. Hunma3

Abstract: In alkalischem Medium (pH 14) entsteht aus dem hydratisierten Dioxocarbonsäureester (Ia) nach Hydrolyse und Benzilsäureumlagerung die Tartronsäure (IIa) als einziges Produkt (Ausb. 85%).

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